Ultrasound-assisted synthesized and catalytic studies of two nano-structured metal–organic frameworks with long N-donor ligand as a pillar
| Autor: | Ali Morsali, Hosein Ghasempour |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Ligand
chemistry.chemical_element Infrared spectroscopy 02 engineering and technology Zinc 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Catalysis Inorganic Chemistry chemistry Reagent Materials Chemistry Metal-organic framework Knoevenagel condensation Physical and Theoretical Chemistry 0210 nano-technology Powder diffraction Nuclear chemistry |
| Zdroj: | Polyhedron. 151:58-65 |
| ISSN: | 0277-5387 |
| Popis: | Facile and environmentally friendly nano-scale synthesis of two new pillared zinc and cadmium metal organic frameworks (MOFs), {[Zn(NH2-BDC)(4-bpmbp)]·2DMF}n (TMU-25) and {[Cd(NH2-BDC)(4-bpmbp)]·2DMF}n (TMU-26), (4-bpmbp = (N4E,N′4E)-N4,N′4-bis(pyridin-4-ylmethylene)-[1,1′-biphenyl]-4,4′-diamine, NH2-BDC = 2-amino-1,4-bnzenedicarboxylate, DMF = N,N′-dimethylformamide), under ultrasonic irradiation at ambient temperature and atmospheric pressure has been explored. These MOFs has been characterized by scanning electron microscopy (FE-SEM), powder X-ray diffraction (PXRD) and IR spectroscopy. Some parameters such as concentration of initial reagents and time effects on shape and size of nano-structured compounds TMU-25 and TMU-26 have been studied. Furthermore, the catalytic behavior of TMU-25 nano-structures toward the Knoevenagel condensation reaction was compared with its bulk form. |
| Databáze: | OpenAIRE |
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