A high performance p-type nickel oxide/cuprous oxide nanocomposite with heterojunction as the photocathodic catalyst for water splitting to produce hydrogen
Autor: | Chunyong Zhang, Xia Li, Dongmei Chu, Ping Yang, Yukou Du, Jie Huang, Aijuan Liu, Yongcheng Zhu, Kezhen Li |
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Rok vydání: | 2018 |
Předmět: |
Nanocomposite
Materials science Hydrogen Nickel oxide General Physics and Astronomy chemistry.chemical_element 02 engineering and technology Photoelectrochemical cell 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences chemistry Chemical engineering Photocatalysis Reversible hydrogen electrode Water splitting Physical and Theoretical Chemistry 0210 nano-technology Hydrogen production |
Zdroj: | Chemical Physics Letters. 703:56-62 |
ISSN: | 0009-2614 |
DOI: | 10.1016/j.cplett.2018.05.020 |
Popis: | An efficient and robust p-type NiO/Cu2O nanocomposite was developed as photocathodic catalyst of a photoelectrochemical cell. The nanocomposite with heterojunction demonstrates enhanced photoelectrochemical (PEC) properties and considerable photocatalytic hydrogen generation ability. When ca. 6 wt.% Cu2O was loaded on the surface of NiO, the sample exhibited the highest photocatalytic activity. The amount of hydrogen evolved from the cathodic chamber of the PEC cell up to 17.6 μmol under 2 h simulated sunlight irradiation with −0.0455 V vs. RHE (reversible hydrogen electrode) bias. |
Databáze: | OpenAIRE |
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