Asymmetric intercoenzyme hydrogen transfer between NADH model compounds and flavins

Autor:	Takaharu Tsuno, Hideki Nakao, Selji Shinkai, Osamu Manabe, Atsuyoshi Ohno
Rok vydání:	1984
Předmět:	chemistry.chemical_classification biology Stereochemistry Hydrogen transfer Riboflavin Flavin group biology.organism_classification Medicinal chemistry Cofactor chemistry.chemical_compound Enzyme Reaction rate constant chemistry biology.protein Molecular Medicine Tetra Magnesium perchlorate
Zdroj:	Journal of the Chemical Society, Chemical Communications. :849
ISSN:	0022-4936
DOI:	10.1039/c39840000849
Popis:	A chiral flavin [(S)-3-methyl-10-(1′-hydroxy-3′-methylbutane-2′-yl)isoalloxazine, (1b)] has been synthesised: hydrogen transfer to (1b) and tetra(O-acetyl)riboflavin from chiral NADH model compounds occurred in an asymmetric manner only in the presence of high concentrations of Mg(ClO4)2.
Databáze:	OpenAIRE
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