Isotope Substitution Effect in Polyatomic Molecules on the Example of 13C2H4 ← 12C2H4 Substitution
| Autor: | K. B. Berezkin, Elena Sergeevna Bekhtereva, I. A. Konov, Sigurd Bauerecker, Olga Vasilievna Gromova, N.V. Kashirina |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Ethylene
010304 chemical physics 010504 meteorology & atmospheric sciences Isotope Polyatomic ion Substitution (logic) General Physics and Astronomy Resonance (chemistry) 01 natural sciences chemistry.chemical_compound chemistry 0103 physical sciences Physical chemistry Molecule Substitution effect Physics::Chemical Physics 0105 earth and related environmental sciences |
| Zdroj: | Russian Physics Journal. 58:1573-1580 |
| ISSN: | 1573-9228 1064-8887 |
| DOI: | 10.1007/s11182-016-0685-z |
| Popis: | General points of the theory of isotope substitution are applied to an analysis of the isotope substitution effect for the substitution 13C2H4←12C2H4 in the ethylene molecule. On the basis of the isotope relations so obtained, numerical predictions of band centers and the most significant rotational, centrifugal, and resonance parameters are made here for the first time for the four lower vibrational states of the 13C2H4 molecule, which can be used to analyze the complicated vibrational-rotational structure of the above-mentioned vibrational states. |
| Databáze: | OpenAIRE |
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