Gold cluster coatings enhancing Raman scattering from surfaces: Ink analysis and document identification

Autor: A. W. Castleman, Zhixun Luo, James H. Adair, Jordan C. Smith, Trevor M. Goff
Rok vydání: 2013
Předmět:
Zdroj: Chemical Physics. 423:73-78
ISSN: 0301-0104
DOI: 10.1016/j.chemphys.2013.06.021
Popis: Based on the method of laser-ablation in liquids (LAL) with a strategy of bubbling nitrogen through a custom-made chamber, we prepared chemically-pure gold clusters which were found to be metastable for an extensive period of time beyond months. A practical use of discrimination among different surfaces is demonstrated here by applying the gold clusters as surface coatings which result in surface-enhanced Raman scattering (SERS) due to the surface plasmon resonance (SPR). This technique identifies various documents from different printers/copiers and written with different pen-inks. The stable and additive-free gold clusters enable repetitive examinations without impurity interference.
Databáze: OpenAIRE