Synthesis and spectroscopic characterization of trihydrido mixed-metal tetranuclear clusters (.mu.-H)3M3Ni(.eta.5-C5H5)(CO)9 (M = Ru, Os). Low-temperature x-ray diffraction study of the osmium derivative

Autor:	Foune Papageorgiou, Guy Lavigne, Jean Jacques Bonnet, Christian Bergounhou
Rok vydání:	1983
Předmět:	Mixed metal Stereochemistry chemistry.chemical_element Nuclear magnetic resonance spectroscopy Crystal structure Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry X-ray crystallography Mass spectrum Osmium Physical and Theoretical Chemistry Derivative (chemistry)
Zdroj:	Inorganic Chemistry. 22:2485-2491
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00160a004
Popis:	Caracterisation des composes par microanalyse, spectrometrie de masse, spectrometrie IR et RMN de 1 H. Le complexe d'osmium cristallise dans le groupe Ccmm avec a=10,274, b=14,735 et c=35,488 A. Affinement jusqu'a R=0,041. Arrangement closo tetraedrique du cœur Os 3 Ni
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::002fc75947eb96b7b96f938ab4f4ebc0 https://doi.org/10.1021/ic00160a004 Zobrazit plný text záznamu