Basic Copper Carbonate-Catalyzed Silyl Conjugate Additions to α,β-Unsaturated Carbonyls in Water
| Autor: | Wang Liansheng, Wei Pengren, Zu-Feng Xiao, Feng Yan, Lei Zhu, Bojie Li, Wang Wei |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Chalcone
Silylation Nitrile 010405 organic chemistry Substrate (chemistry) chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Copper 0104 chemical sciences Catalysis chemistry.chemical_compound chemistry Yield (chemistry) Basic copper carbonate Organic chemistry |
| Zdroj: | Journal of the Chinese Chemical Society. 65:81-86 |
| ISSN: | 0009-4536 |
| DOI: | 10.1002/jccs.201700186 |
| Popis: | We report here the silylation of α,β-unsaturated acceptors in water at room temperature using a copper catalyst. A broad substrate scope, including chalcone derivatives, esters, nitrile, and dienones, has been explored. In all cases, the reaction proceeded well to give the desired products in good to excellent yield. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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