| Popis: |
Formate anion is the simplest carboxylate, compared with other carboxylate, it owns more excellent coordination ability. We used M(OAc)2·n H2O (M=Mn, Cu) as a raw starting material, hydrothermal synthesis methods assisted byDMF hydrolysis which produced the formyl were adopted to prepare metal(II) formates complexes, Mn(HCOO)3·NH2(CH3)2 (1) and Cu(HCOO)3·H3C2O3 (2). The as-prepared products were characterized by elemental analysis, IR spectroscopy, X-ray single-crystal, powder diffraction and thermogravimetric analysis. Structural analysis shows that complex 1 is three-dimensional grid shapes, and complex 2 is a 1D chain structure. |
