| Autor: |
Svitlana R. Petrusenko, Oleg M. Stetsyuk, Irina V. Omelchenko |
| Jazyk: |
angličtina |
| Rok vydání: |
2013 |
| Předmět: |
|
| Zdroj: |
Acta Crystallographica Section E, Vol 69, Iss 6, Pp m326-m327 (2013) |
| ISSN: |
1600-5368 |
| Popis: |
In the title one-dimensional coordination polymer, {[Mn(C10H12NO3)2]I}n, the potentially tetradentate (O,O,O,N) 2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenol (H2L) ligands are mono-deprotonated (as HL−) and coordinated by the metal ions in a tridentate chelate-bridging fashion [2.0111112]. The MnIII atom possesses a distorted trans-MnO4N2 octahedral coordination environment. The bridging ligands lead to [010]-chain polymeric cations {[Mn(HL)2]+}n in the crystal. The charge-balancing iodide ions are disordered over two sites in a 0.690 (2):0.310 (2) ratio and a weak O—H...I hydrogen bond occurs. The crystal studied was found to be a racemic twin. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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