| Autor: |
Koten, G. van, Schaaf, P.A. van der, Smeets, W.J.J., Spek, A.L. |
| Jazyk: |
angličtina |
| Rok vydání: |
1992 |
| Předmět: |
|
| Zdroj: |
Journal of the Chemical Society : Chemical Communications, 1(9), 717. Chemical Society |
| ISSN: |
0022-4936 |
| Popis: |
At 78°C [W(NPh)(CH2SiMe3)3Cl] reacts with 2-[(dimethylamino)methyl]phenyllithium in diethyl ether to produce a tetra-organotungsten(VI) complex which decomposes by an H-elimination reaction generating a novel tungsten(VI) alkylidene with intramolecular coordination of an amine function; this complex reacts with norbornene to provide a cis-polymer that is the result of a selective ring-opening metathesis. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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