Estudo comparativo da eficiência da difenilcarbazida e do óleo de coco saponificado microemulsionados na inibição da corrosão de aço carbono

Autor: Rossi, Cátia G. F. T., Scatena Jr, Hélio, Maciel, Maria Aparecida M., Dantas, Tereza N. C.
Jazyk: portugalština
Rok vydání: 2007
Předmět:
Zdroj: Química Nova v.30 n.5 2007
Química Nova
Sociedade Brasileira de Química (SBQ)
instacron:SBQ
Química Nova, Volume: 30, Issue: 5, Pages: 1128-1132, Published: OCT 2007
Popis: The effectiveness of microemulsions (ME) of saponified coconut oil (OCS-ME) and diphenylcarbazide (DC-ME) on a carbon steel corrosion inhibition process was evaluated using an electrochemical method of polarization resistance. The ME was prepared with OCS, butanol, kerosene and saline solutions. OCS-ME and DC-ME showed highest inhibitions effects (77% and 92%, respectively) at lower concentrations (0.5% and 0.48 - 0.50%, respectively). The surfactant OCS (in H2O) showed lower efficiency (63% at 0.20 - 0.25% concentration). The greatest inhibitory effect of DC-ME could be correlated with the chemical structure and the rich O/W ME system, which are very important for adsorption phenomena in interfacial ME systems.
Databáze: OpenAIRE