An electrochemical impedance study of hydrogen evolution and absorption on Sn-modified steel electrodes
Autor: | Dick, L. F. P., Lisboa, M. B., Castro, Élida Beatriz |
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Jazyk: | angličtina |
Rok vydání: | 2002 |
Předmět: | |
Zdroj: | SEDICI (UNLP) Universidad Nacional de La Plata instacron:UNLP |
Popis: | In this work we report results related to hydrogen evolution and absorption, on AISI 1045 steel and AISI 1045 steel modified by Sn electrodeposition, in 1 M NaOH. The simulation of experimental impedance, steady-state j/E data and electrochemical permeation data in terms of the Volmer–Heyrovsky mechanism coupled to H absorption and diffusion, allowed the estimation of kinetic and transport parameters leading to an appropriate interpretation of diminished H absorption on Sn modified samples. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas |
Databáze: | OpenAIRE |
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