Carbon Tetrachloride as Thermoporometry Liquid-probe to Study the Cross-linking of Styrene Copolymer Networks
| Autor: | Husar, Branislav, Commereuc, Sophie, Lukac, I., Chmela, S., Nedelec, Jean-Marie, Baba, Mohamed |
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| Přispěvatelé: | Photochimie moléculaire et macromoléculaire (PMM), Université Blaise Pascal - Clermont-Ferrand 2 (UBP)-Centre National de la Recherche Scientifique (CNRS), Laboratoire des Matériaux Inorganiques (LMI), Université Blaise Pascal - Clermont-Ferrand 2 (UBP)-Clermont Université-SIGMA Clermont (SIGMA Clermont)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2006 |
| Předmět: | |
| Zdroj: | Journal of Physical Chemistry B Journal of Physical Chemistry B, American Chemical Society, 2006, 110, pp.5315 |
| ISSN: | 1520-6106 1520-5207 |
| Popis: | Mesh Size Distributions (MSDs) of swollen cross linked styrene copolymer networks have been measured by thermoporometry using CCl4 as a probe liquid. All numerical relationships required for the calculation of the MSD were established for both the liquid-to-solid and the solid-to-solid thermal transitions of CCl4 and successfully validated on test samples. It was found that the polymer network, for both thermally and photo-cross linked materials, was completely built in about four hours of exposure. A clear correlation was established between the average mesh size of the swollen polymer network and the benzoyl peroxide groups content. |
| Databáze: | OpenAIRE |
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