Exploring the role of coinage metallates in trifluorometalation: a combined experimental and theoretical study
| Autor: | Martínez de Salinas, Sara, Mudarra, Ángel L., Odena, Carlota, Martínez Belmonte, Marta, Benet-Buchholz, Jordi, Maseras, Feliu, Pérez-Temprano, Mónica H. |
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| Rok vydání: | 2019 |
| Zdroj: | RECERCAT (Dipòsit de la Recerca de Catalunya) Recercat. Dipósit de la Recerca de Catalunya instname |
| Popis: | Despite the known nucleophilic nature of [M(CF3)2]–(M = Cu, Ag, Au), their participation in trifluoromethylation reactions of aryl halides remains unexplored. Herein, we report, for the first time, the selective access to Cu(CF3)2 – species, ubiquitous in Cu-mediated trifluoromethylations, and we rationalize its complex mechanistic scenario and its behavior compared to its silver and gold congeners through a mixture of experimental and computational approaches. |
| Databáze: | OpenAIRE |
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