Rapid synthesis of fused oxabicycles through the molecular rearrangement of spirocyclic ethers
Autor: | Palmer, Leoni I, Veits, Gesine K, de Alaniz, Javier Read |
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Rok vydání: | 2013 |
Předmět: | |
Zdroj: | European Journal of Organic Chemistry, vol 2013, iss 28 Palmer, LI; Veits, GK; & Read De Alaniz, J. (2013). Rapid synthesis of fused oxabicycles through the molecular rearrangement of spirocyclic ethers. European Journal of Organic Chemistry, (28), 6237-6240. doi: 10.1002/ejoc.201300832. UC Santa Barbara: Retrieved from: http://www.escholarship.org/uc/item/1fg13977 |
DOI: | 10.1002/ejoc.201300832. |
Popis: | A molecular rearrangement of 5,5-spirocyclic cyclopentenones to 5,6-fused cyclopentenones catalyzed by Amberlyst®15 is described. This work emphasizes the utility of renewable resources, such as furfural, that can be transformed into a variety of valuable products. It also highlights the viability of 5,5-spirocycles as intermediates en route to 5,6-fused cyclopentenones. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Databáze: | OpenAIRE |
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