Rapid synthesis of fused oxabicycles through the molecular rearrangement of spirocyclic ethers

Autor: Palmer, Leoni I, Veits, Gesine K, de Alaniz, Javier Read
Rok vydání: 2013
Předmět:
Zdroj: European Journal of Organic Chemistry, vol 2013, iss 28
Palmer, LI; Veits, GK; & Read De Alaniz, J. (2013). Rapid synthesis of fused oxabicycles through the molecular rearrangement of spirocyclic ethers. European Journal of Organic Chemistry, (28), 6237-6240. doi: 10.1002/ejoc.201300832. UC Santa Barbara: Retrieved from: http://www.escholarship.org/uc/item/1fg13977
DOI: 10.1002/ejoc.201300832.
Popis: A molecular rearrangement of 5,5-spirocyclic cyclopentenones to 5,6-fused cyclopentenones catalyzed by Amberlyst®15 is described. This work emphasizes the utility of renewable resources, such as furfural, that can be transformed into a variety of valuable products. It also highlights the viability of 5,5-spirocycles as intermediates en route to 5,6-fused cyclopentenones. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Databáze: OpenAIRE