Stratified morphology of a polypropylene/elastomer blend following channel flow

Autor: Moffitt, Matthew, Rharbi, Yahya, Chen, Warner, Tong, Jiang-Dong, A. Winnik *, M., W. Thurman, Derek, P. Oberhauser, James, A. Kornfield, Julia, A. Ryntz, Rose
Přispěvatelé: Laboratoire de rhéologie (LR), Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique de Grenoble (INPG)-Université Joseph Fourier - Grenoble 1 (UJF), Rharbi, Yahya
Jazyk: angličtina
Rok vydání: 2002
Předmět:
Zdroj: Journal of Polymer Science Part B: Polymer Physics
Journal of Polymer Science Part B: Polymer Physics, Wiley, 2002, 40 (24), pp.2842
ISSN: 0887-6266
1099-0488
Popis: International audience; A thermoplastic olefin blend consisting of isotactic polypropylene (PP) and an ethylene-butene copolymer (EBR) impact modifier (25 wt % EBR) was subjected to a short, high-shear pulse within the flow channel of a pressure-driven microextruder following low-shear channel filling from a reservoir of the melt. The resulting morphology was examined by laser scanning confocal fluorescence microscopy (LSCFM), with contrast provided by a fluorescent tracer in the EBR minor phase. Shear experiments were performed under isothermal conditions with a known wall shear stress for a specified duration, providing a well-defined thermal and flow history. Low-shear channel filling produces small droplets across the central region of the channel and large droplets, consistent with steady-state shear, in the regions near the channel walls. After cooling the molten blend to a crystallization temperature of 153 °C, a brief interval (5 s 1/2000 of the quiescent crystallization time) of high shear (wall shear stress: 0.1 MPa) induces rapid, highly oriented crystallization and a stratified morphology. Ex situ LSCFM reveals a skin at the channel walls (70 m) in which greatly elongated fiberlike droplets, oriented along the flow direction, are embedded in highly oriented crystalline PP. Further from the walls but directly beside the skin layers are surprising zones in which EBR domains show no deformation or orientation. Several zones of intermediate deformation and orientation at an angle to the flow direction are located closer to the center of the channel. At the center of the channel, EBR droplets are spherical, as expected for channel flow. The various strata are explained by the interplay of droplet deformation, breakup, and coalescence with the shear-induced crystallization kinetics of the matrix. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 2842-2859, 2002
Databáze: OpenAIRE
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