Structured carbon supports for the immobilization of an Rh diamine complex catalyst

Autor:	Gheorghiu, Constanta Cristina, García-Bordejé, José Enrique, Job, Nathalie, Román Martínez, María del Carmen
Rok vydání:	2016
Předmět:	Hybrid catalyst Carbon xerogels CNF-monolith Structured supports
Zdroj:	Digital.CSIC. Repositorio Institucional del CSIC instname
Popis:	Hybrid catalysts were prepared by anchoring covalently an Rh diamine complex in two very different structured carbon materials: a ceramic monolith coated with carbon nanofibres and a mesoporous carbon xerogel. The morphology of these catalysts allows an easy separation from the reaction media. The obtained catalysts are noticeably more active than the homogeneous Rh complex and they are stable against leaching. After a first use, a partial reduction of the Rh complex takes place and nanometric Rh particles are developed, which increases the catalyst activity. The catalyst prepared with the ceramic monolith coated with carbon fibres shows noteworthy advantages like easy handling, immediate recovery and removal from the reaction media, and good mechanical strength. The authors thank the financial support through public projects of reference: MAT2012-32832 and PROMETEO/II/2014/010.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::b9a8be01953e42eedc76d3fd624cb513 http://hdl.handle.net/10261/134664 Zobrazit plný text záznamu