Controllable Direction of Porphyrin Derivatives in Two Cyclodextrin Cavities
| Autor: | Horiguchi, Banri, Nakaya, Toshimi, Ueda, Masafumi, Sugikawa, Kouta, Mizuta, Tsutomu, Haino, Takeharu, Kawata, Naomi, Ikeda, Atsushi |
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| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: | |
| Zdroj: | European Journal of Organic Chemistry. 2018(18):2138-2143 |
| Popis: | Porphyrin-trimethyl-β-cyclodextrin (TMe-β-CDx) complexes have pseudorotaxane structures in which two mesophenyl and/or pyridyl moieties penetrate the upper rim of two TMe-β-CDx molecules. Porphyrin derivatives with one to three pyridyl moieties at meso-positions formed complexes with TMe-β-CDx in which penetration of the upper rim of the two TMe-β-CDxs by the pyridyl moieties was minimized. In contrast, in TMe-β-CDx complexes formed with porphyrin derivatives with two 2-methoxyphenyl moieties and two pyridyl moieties, the pyridyl moieties penetrated the upper rim of the two molecules because steric hindrance prevented penetration by the 2-methoxyphenyl moieties. This work was supported by a JSPS KAKENHI Grant-in-Aid for Scientific Research (B) (Grant No. JP16H04133), a Grant-in-Aid for Challenging Exploratory Research (Grant No. JP16K13982), and the Electric Technology Research Foundation of Chugoku. |
| Databáze: | OpenAIRE |
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