Ferrofluidic aqueous two-phase system with ultralow interfacial tension and micro-pattern formation

Autor: Rigoni, Carlo, Beaune, Grégory, Harnist, Bent, Sohrabi, Fereshteh, Timonen, Jaakko V.I.
Přispěvatelé: Active Matter, Department of Applied Physics, Aalto-yliopisto, Aalto University
Jazyk: angličtina
Zdroj: Communications Materials. 3(1)
ISSN: 2662-4443
DOI: 10.1038/s43246-022-00249-z
Popis: openaire: EC/H2020/803937/EU//InterActive Funding Information: J.V.I.T. acknowledges funding from ERC (803937) and Academy of Finland (316219). We acknowledge the facilities and technical support by Aalto University at OtaNano Nanomicroscopy Centre (Aalto-NMC). Publisher Copyright: © 2022, The Author(s). Ferrofluids are magnetic liquids known for the patterns they form in external magnetic fields. Typically, the patterns form at the interface between a ferrofluid and another immiscible non-magnetic fluid with a large interfacial tension γ ∼ 10−2 N m−1, leading to large pattern periodicities. Here we show that it is possible to reduce the interfacial tension several orders of magnitude down to ca. γ ∼ 10−6 N m−1 by using two immiscible aqueous phases based on spontaneous phase separation of dextran and polyethylene glycol and the asymmetric partitioning of superparamagnetic maghemite nanoparticles into the dextran-rich phase. The system exhibits classic Rosensweig instability in a uniform magnetic field with a periodicity of ∼200 μm, significantly lower than in traditional systems (∼10 mm). This system paves the way towards the science of pattern formation at the limit of vanishing interfacial tension and ferrofluid applications driven by small external magnetic fields.
Databáze: OpenAIRE