C-C bond formation via N-phosphoryliminium ions
Autor: | Kinderman, S.S., Maarseveen, J.H. van, Schoemaker, H.E., Hiemstra, H., Rutjes, F.P.J.T. |
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Přispěvatelé: | Synthetic Organic Chemistry (HIMS, FNWI) |
Rok vydání: | 2004 |
Předmět: | |
Zdroj: | Synthesis, 9, 1413-1418. Georg Thieme Verlag Synthesis : International Journal of Methods in Synthetic Organic Chemistry, 2004, 9, pp. 1413-1418 Synthesis : International Journal of Methods in Synthetic Organic Chemistry, 2004, 1413-1418 |
ISSN: | 0039-7881 |
Popis: | Contains fulltext : 57310.pdf (Publisher’s version ) (Closed access) This paper describes preliminary results in the field of rather unexplored nucleophilic additions to N-phosphoryliminium ions. The synthesis of allylic and non-allylic cyclic amidophosphate-based N,O-acetals and their application in C-C bond formation is detailed. In addition, the influence of a chiral auxiliary on the phosphorus atom has been investigated. |
Databáze: | OpenAIRE |
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