C-C bond formation via N-phosphoryliminium ions

Autor: Kinderman, S.S., Maarseveen, J.H. van, Schoemaker, H.E., Hiemstra, H., Rutjes, F.P.J.T.
Přispěvatelé: Synthetic Organic Chemistry (HIMS, FNWI)
Rok vydání: 2004
Předmět:
Zdroj: Synthesis, 9, 1413-1418. Georg Thieme Verlag
Synthesis : International Journal of Methods in Synthetic Organic Chemistry, 2004, 9, pp. 1413-1418
Synthesis : International Journal of Methods in Synthetic Organic Chemistry, 2004, 1413-1418
ISSN: 0039-7881
Popis: Contains fulltext : 57310.pdf (Publisher’s version ) (Closed access) This paper describes preliminary results in the field of rather unexplored nucleophilic additions to N-phosphoryliminium ions. The synthesis of allylic and non-allylic cyclic amidophosphate-based N,O-acetals and their application in C-C bond formation is detailed. In addition, the influence of a chiral auxiliary on the phosphorus atom has been investigated.
Databáze: OpenAIRE