The mechanisms of tris(4-morpholinecarbodithioato-S,S′)cobalt(III) complex formation by solid state reaction from ammine cobalt(III) complexes

Autor:	Sabo, T. J., Vlajković, J., Vera Dondur
Rok vydání:	1997
Předmět:	Kinetic Cobalt(III) complexes Potassium 4-morpholinecarbodithioate Mechanism Pentaamminechlorocobalt(III) chloride
Zdroj:	Journal of the Serbian Chemical Society Scopus-Elsevier
Popis:	In this paper, the solid state reaction, conducted with a mixture of pentaamminechlorocobalt(III) chloride and potassium 4-morpholinecarbodithioate was investigated under isothermal conditions. The reaction proceeds at relatively low temperatures (154-192 °C). The yield of product solid-solid reaction, tris(4-morpholinecarbodithioato-S,S')cobalt(III) complex, does not exceed 65%. The kinetic of the reaction of powdered and pressed samples were investigated. The reaction proceeded according to the diffusional mechanism. Activation energies of 200 kJ/mol and 100 kJ/mol for the powdered and pressed form, respectively, were obtained.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::a381c22f0aecfba70b7d40c9769be754 http://cherry.chem.bg.ac.rs/handle/123456789/46 Zobrazit plný text záznamu