Phosphinic acids as inorganic bridging ligands for the 1D self-assembly of Mn(II) complexes
| Autor: | Richeter, Sébastien, Leclercq, Dominique, Van Der Lee, Arie, Larionova, Joulia |
|---|---|
| Přispěvatelé: | Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC), Chimie moléculaire et organisation du solide (CMOS), Université Montpellier 2 - Sciences et Techniques (UM2)-Centre National de la Recherche Scientifique (CNRS), Institut Européen des membranes (IEM), Centre National de la Recherche Scientifique (CNRS)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM) |
| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | ICOMC 2008 XXIII International Conferenceon Organometallic Chemistry 2008 XXIII International Conferenceon Organometallic Chemistry 2008, Jul 2008, Rennes, France. pp.P369 |
| Popis: | International audience; The construction of supramolecular structures by self-assembly of metal complexes and linkers has attracted a broad interest during the last decade. Tetradendate ligands like salen derivatives, phthlocyanines or porphyrins, which are able to block the equatorial positions of octahedral metals, have been used for the preparation of 1D structures. In this communication, we will report the use of phosphinic acids as linkers for the construction of 1D polymeric chains by self-assembling manganese (III) complexes of salen ligands. Depending on the nature of the salen ligand and the phosphinate derivatives, monomeric, dimeric or polymeric structures have been obtained. The magnetic properties of these compounds will be reported. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|