Nanometric TiO 2 as NBBs for functional organic-inorganic hybrids with efficient interfacial charge transfer
| Autor: | Gorbovyi, P., Traoré, M., Chhor, K., Museur, Luc, Kuznetsov, A., Chichkov, B.N., Kanaev, A.V. |
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| Přispěvatelé: | Laboratoire d'Ingénierie des Matériaux et des Hautes Pressions (LIMHP), Université Paris 13 (UP13)-Institut Galilée-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Physique des Lasers (LPL), Université Paris 13 (UP13)-Centre National de la Recherche Scientifique (CNRS), Laser Zentrum Hannover e.V. (LZH) |
| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Chemical Engineering Transactions Chemical Engineering Transactions, AIDIC, 2011, ⟨10.3303/CET1124033⟩ |
| ISSN: | 2283-9216 |
| DOI: | 10.3303/CET1124033⟩ |
| Popis: | International audience; The purpose of this work is to establish a fabrication method for new electronic materials: organic-inorganic p-MAPTMS / titanium-oxo-alkoxy hybrids. The size-selected 5.2-nm TiO 2 nanoparticles (Nano Building Blocks-NBB) are generated in a sol-gel reactor with turbulent fluids micromixing. The surface exchange between propoxy and MAPTMS groups under vacuum pumping results in a stable nanoparticulate precursor available for 2-photon laser polymerisation. The hybrids demonstrate quantum yield of photoinduced charges separation 6 % and can steadily trap photoinduced electrons at number density of 6% Ti atoms. The materials are suitable for 3D-microstructuring. |
| Databáze: | OpenAIRE |
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