Poly(diphenylacetylene)s: Design, Synthesis and Application
| Autor: | Tarrío Cordeiro, Juan José |
|---|---|
| Přispěvatelé: | Quiñoá Cabana, Emilio, Freire Iribarne, Félix, Universidade de Santiago de Compostela. Escola de Doutoramento Internacional (EDIUS), Universidade de Santiago de Compostela. Programa de Doutoramento en Ciencia e Tecnoloxía Química |
| Jazyk: | angličtina |
| Rok vydání: | 2022 |
| Předmět: |
Investigación::23 Química::2306 Química orgánica::230616 Esteroquímica y análisis conformacional [Materias]
Helical Polymers Secondary Structure Investigación::23 Química::2304 Química macromolecular::230423 Síntesis de macromoléculas [Materias] Investigación::23 Química::2304 Química macromolecular::230416 Análisis de polímeros [Materias] Poly(diphenylacetylene)s CPL materials |
| Zdroj: | Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela instname |
| Popis: | This Doctoral Thesis is focused on the development of new chiral materials based on poly(diphenylacetylene)s (PDPA). PDPAs are a family of helical polymers generally described as very stable and static, where the secondary structure —helical sense and/or elongation— cannot be modulated by external stimuli. Therefore, in this work we have explored different approaches to synthesize the first reported dynamic PDPAs, which has allowed us to create new stimuli-responsive materials. In addition, we have also focused on the elucidation of the secondary structure of those polymers to understand their structure-function relationship. These results can help the future rational design of novel smart materials with specific properties. |
| Databáze: | OpenAIRE |
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