Trinuclear palladium(II) complexes with 2-hydroxy-4-methoxyacetophenone N-4-dimethylthiosemicarbazone: Synthesis, spectral studies and crystal structure of a tripalladium complex

Autor:	Kovala-Demertzi, D., Nikolaos Kourkoumelis, Demertzis, M. A., Miller, J. R., Frampton, C. S., Swearingen, J. K., West, D. X.
Jazyk:	angličtina
Rok vydání:	2000
Předmět:	one-dimensional extended networks molecular-structure structure elucidation copper(ii) complexes in-vitro palladium ligand s ligands nickel(ii) complexes 2-hydroxyacetophenone n-4-substituted thiosemicarbazones antitumor-activity pd(ii) derivatives acetate
Zdroj:	Scopus-Elsevier
Popis:	The synthesis and spectral characterization of a new triangular, trinuclear palladium(II) complex with the dianion of 2-hydroxy-4-methoxyacetophenone N-4-dimethylthiosemicarbazone, 4MeOAp4Me(2)(2-) is reported. The X-ray crystal structure determination of [Pd(4MeOAp4Me(2))](3). DMSO shows it to contain a chair-type hexagon of alternating Pd and S atoms which form a molecular bowl. The crystal structure of H(2)4MeOAp4Me(2) shows that it is the E isomer with respect to the imine bond of the thiosemicarbazone moiety. European Journal of Inorganic Chemistry
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::78618f18a59c1b4108d17af181b1a8b3 http://olympias.lib.uoi.gr/jspui/handle/123456789/9790 Zobrazit plný text záznamu