RELATION BETWEEN MECHANICAL PROPERTIES AND PYROLYSIS TEMPERATURE OF PHENOL FORMALDEHYDE RESIN FOR GAS SEPARATION MEMBRANES
Autor: | Šupová, M., Svítilová, J., Chlup, Z., Martin Černý, Weishauptová, Z., Suchý, T., Machovič, V., Sucharda, Z., Žaloudková, M. |
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Jazyk: | angličtina |
Rok vydání: | 2012 |
Předmět: | |
Zdroj: | Ceramics-Silikáty, Vol 56, Iss 1, Pp 40-49 (2012) Scopus-Elsevier |
ISSN: | 1804-5847 0862-5468 |
Popis: | The aim of this paper has been to characterize the relation between the pyrolysis temperature of phenol-formaldehyde resin, the development of a porous structure, and the mechanical properties for the application of semipermeable membranes for gas separation. No previous study has dealt with this problem in its entirety. Phenol-formaldehyde resin showed an increasing trend toward micropore porosity in the temperature range from 500 till 1000°C, together with closure of mesopores and macropores. Samples cured and pyrolyzed at 1000°C pronounced hysteresis of desorption branch. The ultimate bending strength was measured using a four-point arrangement that is more suitable for measuring of brittle materials. The chevron notch technique was used for determination the fracture toughness. The results for mechanical properties indicated that phenol-formaldehyde resin pyrolyzates behaved similarly to ceramic materials. The data obtained for the material can be used for calculating the technical design of gas separation membranes. |
Databáze: | OpenAIRE |
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