| Autor: |
Cailler, L., Sorokin, A. B., Kroitor, A-P., Martynov, A-G., Gorbunova, Y-G., Tsivadze, A-Y. |
| Přispěvatelé: |
IRCELYON-C'Durable (CDURABLE), Institut de recherches sur la catalyse et l'environnement de Lyon (IRCELYON), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), IRCELYON, ProductionsScientifiques |
| Jazyk: |
angličtina |
| Rok vydání: |
2018 |
| Předmět: |
|
| Popis: |
SSCI-VIDE+CDFA+LCL:ASO; International audience; Carbene transfer reactions catalyzed by metal complexes are widely used in organic chemistry. Due to high versatility of this synthetic strategy involving metal carbene complexes, a large range of elaborated compounds can be prepared via cyclopropanation of olefins and carbene insertion into C-H, N-H and O-H bonds. Among the metal complexes, metalloporphyrins have been extensively studied as catalysts for the carbene transfer reactions. In contrast, their phthalocyanine counterparts have been rarely used. We present here the first detailed study of the application of several phthalocyanine complexes for the large-scope intermolecular cyclopropanation of olefins. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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