Synthesis and structural characterisation of [Cu2[(PDC)2(bpa)(H2O)2]•nH2O•mDMF (n=3 and m=1 for 1, n=7 and m=0 for 2, PDC=2,5-pyrindinedicarboxylate and bpa= 1,2-di(4-pyridil)ethane))
| Autor: | Bazán Blau, Begoña del Pilar, Barandika Argoitia, Miren Gotzone, Llano Tomé, Francisco, Urtiaga Greaves, Miren Karmele, Arriortua Marcaida, María Isabel |
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| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: | |
| Zdroj: | Addi. Archivo Digital para la Docencia y la Investigación instname |
| Popis: | [EN] Combination of polycarboxylate anions and dipyridyl ligands is an effective strategy to produce solid coordination frameworks (SCF) which are crystalline materials based on connections between metal ions through organic ligands. In this sense, combination of polycarboxylate anions and dipyridyl ligands is an effective strategy to produce extended structures. In this context, this work is focused on two novel CuII-based SCFs exhibiting PDC (2,5-pyridinedicarboxylate) and bpa (1,2-di(4-pyridyl)ethane), being the first structures reported in literature containing both ligands. Chemical formula are [Cu2[(PDC)2(bpa)(H2O)2]•3H2O•DMF (1), and [Cu2(PDC)2(bpa)(H2O)2]•7H2O (2), where DMF is dimethylformamide. Compounds 1 and 2 have been characterized by means of XRD, IR, TG/DTG, and DTA analysis. Ministerio de Economía y Competitividad (MAT2013-42092-R, FEDER MAT2010-21342-C02-01), Gobierno Vasco (Basque University System Research Group, IT-630-13, UPV/EHU (UFI 11/15), Ministerio de Ciencia e Innovación(BES-2011-045781). |
| Databáze: | OpenAIRE |
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