Allylation and propargylation of chiral cyanopropanoates: An efficient route to long chain α-substituted α-methyl α-amino acids

Autor:	Cativiela, Carlos, Díaz de Villegas, María D., Gálvez, José A., Ronco, Eva
Přispěvatelé:	Ministerio de Ciencia y Tecnología (España), European Commission
Rok vydání:	2004
Zdroj:	Digital.CSIC. Repositorio Institucional del CSIC instname
Popis:	α-Methyllysine and 2-amino-2-methylundecanoic acid, two α,α-disubstituted unnatural glycines, were synthesized using highly diastereoselective allylation or propargylation of chiral (1S,2R,4R)-10-dicyclohexylsulfamoylisobornyl 2-cyanopropanoate as the key step to introduce the long side chain. Contract grant sponsors: Ministerio de Ciencia y Tecnologia and FEDER; Contract grant number: PPQ2001-1834.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::52a1cef446347e897bd99bfd487e917e http://hdl.handle.net/10261/270931 Zobrazit plný text záznamu