Study of Iodine-Olefin Complexes
| Autor: | Toma, Shitoku, Kinjo, Yoshiaki, Kinjo, Akio |
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| Jazyk: | japonština |
| Rok vydání: | 1972 |
| Zdroj: | 琉球大学理工学部紀要. 理学編. (15):51-58 |
| Popis: | Charge- transfer complexes between iodine and olefins were studied spectrophotometrically in n- hexane solutions. The experiments were carried out in the room with a dim light to avoid the addition reaction. The equilibrium constants were determined to be 0.52, 1.ll, 0.44, 0.63 and 1.73 l./mol for l - hexene, I-heptene, 1 - octent, 1 - decent and cyclohexene complex at 25℃. The heat of formation and enthropy change fall in the range of - l.71 ~ -2 .28 Kcal /mol and of -6.01~ - 7.37 e. u., respectimcly.\n 紀要論文 |
| Databáze: | OpenAIRE |
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