Isotope effect in the gas phase reaction of pyrene-D10 with Nb+ ions

Autor:	Kazazić, S., Klasinc, L., Marko Rozman, Srzić, D., Knop, J.
Jazyk:	angličtina
Rok vydání:	2004
Předmět:	Chemistry parasitic diseases gas phase reaction Fourier transform mass spectrometry deuterium kinetic isotope effect niobium (II) pyrene pyrene-d10 pyrene-D10
Zdroj:	Croatica Chemica Acta Volume 77 Issue 1-2 Scopus-Elsevier
ISSN:	0011-1643 1334-417X
Popis:	The deuterium isotope effect in the gas phase ligation of niobium (Nb) monocations by a mixture of pyrene and perdeutero pyrene was studied in a FTMS instrument. The attachment of pyrene (pyrene-d(10)) is followed by a rapid release of hydrogen (deuterium) from the Nb-pyrene (Nb-pyrene-d(10)) cation, respectively. The dehydrogenated product formation depends on the experimental conditions in the reaction chamber. A 1,2-elimination of H-2 (D-2) from the ligation product is proposed.
Databáze:	OpenAIRE
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