Photoassisted Dehydrogenation of 2-Propanol in the Liquid Phase with Hydrido (phosphonite) cobalt (I)
| Autor: | Onishi, Masayoshi, Hiraki, Katsuma, Nishimura, Kohsei |
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| Jazyk: | angličtina |
| Rok vydání: | 1996 |
| Zdroj: | 長崎大学工学部研究報告. 26(46):113-116 |
| ISSN: | 0286-0902 |
| Popis: | Hydrido (phosphonite) cobalt(I) [CoH{PPh(OEt)_2}_4], (CoHL_4) (L=PPh(OEt)_2) under Pyrex-filtered photoirradiation catalyzed dehydrogenation reaction of 2-propanol in the liquid phase, with release of acetone. The turn-over number evaluated for the dehydrogenation for 1h at 82℃ was 4.6, and the quantum yields for the reaction at 366nm were determined to be about 0.015 at 60 and 82℃. The dehydrogenation was characterized as a photoassisted-type catalytic reaction, and the photogenerated hydrido transient CoHL_3 was attributed to a key-role-playing intermediate in the catalytic cycle of the dehydrogenation. 長崎大学工学部研究報告 Vol.26(46) p. 113-116, 1996 |
| Databáze: | OpenAIRE |
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