Chemical Conversion of Linkages in Covalent Organic Frameworks
| Autor: | Waller, PJ, Lyle, SJ, Osborn Popp, TM, Diercks, CS, Reimer, JA, Yaghi, OM |
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| Rok vydání: | 2016 |
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| Zdroj: | Journal of the American Chemical Society, vol 138, iss 48 Waller, PJ; Lyle, SJ; Osborn Popp, TM; Diercks, CS; Reimer, JA; & Yaghi, OM. (2016). Chemical Conversion of Linkages in Covalent Organic Frameworks. Journal of the American Chemical Society, 138(48), 15519-15522. doi: 10.1021/jacs.6b08377. UC Berkeley: Retrieved from: http://www.escholarship.org/uc/item/4tb7k4z0 |
| Popis: | © 2016 American Chemical Society. The imine linkages of two layered, porous covalent organic frameworks (COFs), TPB-TP-COF ([C6H3(C6H4N)3]2[C6H4(CH)2]3, 1) and 4PE-1P-COF ([C2(C6H4N)4][C6H4(CH)2]2, 2), have been transformed into amide linkages to make the respective isostructural amide COFs 1′ and 2′ by direct oxidation with retention of crystallinity and permanent porosity. Remarkably, the oxidation of both imine COFs is complete, as assessed by FT-IR and13C CP-MAS NMR spectroscopy and demonstrates (a) the first chemical conversion of a COF linkage and (b) how the usual “crystallization problem” encountered in COF chemistry can be bypassed to access COFs, such as these amides, that are typically thought to be difficult to obtain by the usual de novo methods. The amide COFs show improved chemical stability relative to their imine progenitors. |
| Databáze: | OpenAIRE |
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