Mono-DMSO ligated cobalt nitrophenylcorroles: electrochemical and spectral characterization
| Autor: | Jiang, Xiaoqin, Shan, Wengian, Desbois, Nicolas, Quesneau, Valentin, Brandès, Stéphane, Van Caemelbecke, E, Osterloh, W, Patissier, Virginie, Gros, C, Kadish, Karl M |
|---|---|
| Přispěvatelé: | University of Houston, Franche-Comté Électronique Mécanique, Thermique et Optique - Sciences et Technologies (UMR 6174) (FEMTO-ST), Université de Technologie de Belfort-Montbeliard (UTBM)-Ecole Nationale Supérieure de Mécanique et des Microtechniques (ENSMM)-Université de Franche-Comté (UFC), Université Bourgogne Franche-Comté [COMUE] (UBFC)-Université Bourgogne Franche-Comté [COMUE] (UBFC)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: | |
| Zdroj: | New Journal of Chemistry New Journal of Chemistry, Royal Society of Chemistry, 2018, 42 (10), pp.8220-8229 |
| ISSN: | 1144-0546 1369-9261 |
| Popis: | International audience; Four mono-DMSO ligated cobalt corroles with one or three meso-nitrophenyl substituents on the macrocycle were synthesized and investigated as to their electrochemical and spectroscopic properties in CH2Cl2 and DMSO. Comparisons are made between redox reactions of the five-coordinate DMSO adducts in the current study and earlier examined five- and six-coordinate cobalt corroles with pyridine axial ligands which were characterized in a variety of nonaqueous electrochemical solvents. The binding of carbon monoxide (CO) is also investigated. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|