| Autor: |
Norquist, AJ, Doran, MB, Thomas, PM, O'Hare, D |
| Jazyk: |
angličtina |
| Rok vydání: |
2016 |
| Popis: |
The potential of organic amine templates to direct the synthesis of metal sulfate frameworks has been investigated. Eight novel uranyl sulfates have been prepared using a templated uranyl sulfate precursor under hydrothermal conditions. The topologis of the isolated phases vary from the molecular (0-D), to chains (1-D) to layered (2-D) frameworks. [N4C6H 22]2[(UO2)2(SO4) 6] (USO-10) is molecular or zero-dimensional. Two different types of onedimensional uranyl-containing chains have been observed. [N2C 4H12][UO2(H2O)(SO4) 2 (USO-3), [N2C5H14]-[UO 2(H2O)(SO4)2] (USO-4) and [N 2C3H12][UO2(H2O)(SO 4)2 (USO-9) contain chains based upon a [UO 2(SO4)4/2] backbone. [N2C 10H10][UO2(SO4)2· H2O (USO-6) and [N2C6H18][(UO 2)2(H2O)3(SO4) 3] (USO-7) contain chains based upon a [UO2(SO 4)3/3] backbone. Two layered or two-dimensional compounds, [N2C6H14][UO2(H2O) (SO4)2 (USO-5) and [N2C3H 5]2[(UO2)2(SO4) 3] (USO-8) have also been isolated. All the new phases have been characterised using a range of physical techniques including single crystal X-ray structure analysis. © The Royal Society of Chemistry 2003. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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