Stepwise Bay Annulation of Indigo for the Synthesis of Desymmetrized Electron Acceptors and Donor-Acceptor Constructs
| Autor: | Kolaczkowski, Matthew A, He, Bo, Liu, Yi |
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| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: | |
| Zdroj: | Kolaczkowski, MA; He, B; & Liu, Y. (2016). Stepwise Bay Annulation of Indigo for the Synthesis of Desymmetrized Electron Acceptors and Donor-Acceptor Constructs. Organic Letters, 18(20), 5224-5227. doi: 10.1021/acs.orglett.6b02504. Lawrence Berkeley National Laboratory: Retrieved from: http://www.escholarship.org/uc/item/0nc2n0qn Organic letters, vol 18, iss 20 |
| DOI: | 10.1021/acs.orglett.6b02504. |
| Popis: | © 2016 American Chemical Society. A selective stepwise annulation of indigo has been demonstrated as a means of providing both monoannulated and differentially double-annulated indigo derivatives. Disparate substitution of the electron accepting bay-annulated indigo system allows for fine control over both the electronic properties as well as donor-acceptor structural architectures. Optical and electronic properties were characterized computationally as well as through UV-vis absorption spectroscopy and cyclic voltammetry. This straightforward method provides a modular approach for the design of indigo-based materials with tailored optoelectronic properties. |
| Databáze: | OpenAIRE |
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