Anti-agglomerant performance of surfactants evaluated in cyclopentane hydrate and CH4/C3H8 gas hydrate systems
Autor: | Delroisse, Henry, Torré, Jean-Philippe, Baretto, Gilles, Jorda, Eric, Glenat, Philippe, Dicharry, Christophe |
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Přispěvatelé: | Laboratoire des Fluides Complexes et leurs Réservoirs (LFCR), TOTAL FINA ELF-Université de Pau et des Pays de l'Adour (UPPA)-Centre National de la Recherche Scientifique (CNRS), Arkema (Arkema), Total (FRANCE), Arkema (FRANCE), Centre National de la Recherche Scientifique - CNRS (FRANCE), Université de Pau et des Pays de l'Adour - UPPA (FRANCE) |
Jazyk: | angličtina |
Rok vydání: | 2017 |
Předmět: | |
Zdroj: | 9th International Conference on Gas Hydrates (ICGH9) 9th International Conference on Gas Hydrates (ICGH9), Jun 2017, Denver, United States. pp.0 |
Popis: | International audience; The main objective of this work was to evaluate and compare the AA performance of surfactants of different affinity in cyclopentane (CP) hydrate and gas (methane – propane mixture) hydrate systems. The study was performed with two surfactants: Noramium® DA 50 and Inipol® AH 81, which are respectively water-soluble and dispersible in water. Their AA performance was evaluated and compared without or with 4 wt% NaCl. A comparative study of the effect of the surfactants on the water/CP interfacial activity was carried out by surface pressure measurements. The impact of the surfactants on hydrate formation and morphology was observed by microscopic observations at the water/CP interface. Lastly, the AA performance of DA 50 and AH 81, was evaluated at the macroscopic scale in a batch reactor under agitation. The experiments in reactor were performed in oil-dominated systems (70 vol%) with CP as the oil phase in the CP hydrate system, and n-octane in the gas hydrate one. |
Databáze: | OpenAIRE |
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