Comparison of the reactivity of the low buried-volume carbene complexes (ITMe)2Pd(PhC≡CPh) and (ITMe)2Pd(PhN=NPh)

Autor:	Ansell, Melvyn B, Furfari, Samantha K, Cloke, F Geofffrey N, Roe, S Mark, Spencer, John, Navarro, Oscar
Jazyk:	angličtina
Rok vydání:	2018
Předmět:	QD0901 QD0411 QD QD0241
ISSN:	0276-7333
Popis:	The novel Pd(0)-azobenzene complex (ITMe)2Pd(PhN=NPh) (5) (ITMe = 1,3,4,5-tetramethylimidazol 2-ylidene) has been isolated and characterized in the solid state and by cyclic voltammetry. Its reactivity towards E-E’ bonds (E, E’= Si, B, Ge) has been compared with that of the known palladium carbene complex (ITMe)2Pd(PhC≡CPh) (2). Whereas 2 reacts with all E-E’ bonds studied, 5 only reacted with B-B and B-Si moieties, echoing our previous catalytic studies on azobenzenes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=core_ac_uk__::f352fd1535b68c94a8c78b6196f06635 http://sro.sussex.ac.uk/id/eprint/74606/3/acs.organomet.8b00112.pdf Zobrazit plný text záznamu