| Autor: |
Tumanov, SV, Veber, SL, Greatorex, S, Halcrow, MA, Fedin, MV |
| Jazyk: |
angličtina |
| Rok vydání: |
2018 |
| ISSN: |
0020-1669 |
| Popis: |
Q-band electron paramagnetic resonance (EPR) data conclusively demonstrate that the iron and cobalt centers in the solid solution [Fe(bpp)₂]₀.₉₇[Co(terpy)₂]₀.₀₃[BF₄]₂ (bpp = 2,6-dipyrazol-1-ylpyridine) undergo allosteric spin-state switching during light-induced excited-spin-state trapping (LIESST) at 20 K and thermal relaxation around 80 K. EPR of [Cu(terpy)₂]²⁺ and [Cu(bpp)₂]²⁺, doped into the same host lattice, also indicates expansion of the copper coordination sphere during LIESST excitation. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
|
