Autor: |
Vorotnikova, Natalya A., Edeleva, Mariya V., Kurskaya, Olga G., Brylev, Konstantin A., Shestopalov, Alexander M., Mironov, Yuri V., Sutherland, Andrew J., Efremova, Olga A., Shestopalov, Michael A. |
Jazyk: |
angličtina |
Rok vydání: |
2017 |
ISSN: |
1097-0126 |
Popis: |
Molybdenum octahedral clusters, when incorporated into an appropriate polymer matrix, are considered as promising agents for a range of biological applications. This work describes the one-pot synthesis, morphology and cellular toxicity of nano-sized polystyrene beads doped with luminescent cluster complexes [(Mo6X8)(NO3)6]2- (X=Cl, Br or I). Specifically, the particles were obtained by free radical dispersion copolymerisation of styrene and methacrylic acid or 4-vinylpyridine in the presence of the cluster complexes. The effects of the cluster loading in the reaction mixture on both the content of the final material and number-average molar mass of the copolymers were evaluated. |
Databáze: |
OpenAIRE |
Externí odkaz: |
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