Reducing properties of 1,2 - diaryl - 1,2 - disodiumethanes

Autor: Azzena U., Pittalis M., Dettori G., Madeddu S., Azara E.
Rok vydání: 2006
Zdroj: Tetrahedron letters 47 (2006): 1055–1058.
info:cnr-pdr/source/autori:Azzena U.,Pittalis M., Dettori G., Madeddu S., Azara E./titolo:Reducing properties of 1,2-diaryl-1,2-disodiumethanes/doi:/rivista:Tetrahedron letters/anno:2006/pagina_da:1055/pagina_a:1058/intervallo_pagine:1055–1058/volume:47
Popis: 1,2-Diphenyl- and 1-phenyl-2-(2-pyridyl)-1,2-disodiumethane efficiently dehalogenate vic-dibromoderivatives, affording the corresponding alkenes. The reaction proceeds rapidly, under mild conditions, and is tolerant of a variety of functional groups (alcohol, carboxylic acid, ester, amide). This procedure was successfully extended to similar vic-disubstituted compounds.
Databáze: OpenAIRE