A Zn(II) Metallocycle as Platform to Assemble a 1D

Autor:	Rancan M., Truccolo G., Carlotto A., Quici S., Armelao L.
Jazyk:	angličtina
Rok vydání:	2019
Předmět:	metalloring zinc ancillary ligand self-assembly polyrotaxane metallocycle pi stacking
Zdroj:	Inorganics 7 (2019). doi:10.3390/inorganics7110137 info:cnr-pdr/source/autori:Rancan M.; Truccolo G.; Carlotto A.; Quici S.; Armelao L./titolo:A Zn(II) Metallocycle as Platform to Assemble a 1D/doi:10.3390%2Finorganics7110137/rivista:Inorganics/anno:2019/pagina_da:/pagina_a:/intervallo_pagine:/volume:7
DOI:	10.3390/inorganics7110137
Popis:	A new [Zn2L2] metallocycle bearing two metal centers that can coordinate ancillary ligands and a pocket suitable to host guest molecules is reported. These two features are exploited by reacting the metallocycle with a pyridine ligand to self-assemble in the solid state an extended intertwined system with the rare 1D + 1D -> 1D topology. This interpenetrated architecture is supported by ?...? stacking between two pyridine units of two different metallocycles in the pocket of a third metallocycle.
Databáze:	OpenAIRE
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