Stereoselective hetero Diels-Alder reactions of chiral tricarbonyl(eta-6-benzaldehyde)chromium complexes
| Autor: | Baldoli, C., Maiorana, S., Licandro, E., Zinzalla, G., Lanfranchi, M., Tiripicchio |
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| Jazyk: | angličtina |
| Rok vydání: | 2001 |
| Předmět: | |
| Zdroj: | Tetrahedron: asymmetry (Online) 12 (2001): 2159–2167. doi:10.1016/S0957-4166 info:cnr-pdr/source/autori:Baldoli, C.; Maiorana, S.; Licandro, E.; Zinzalla, G.; Lanfranchi, M.; Tiripicchio/titolo:Stereoselective hetero Diels-Alder reactions of chiral tricarbonyl(eta-6-benzaldehyde)chromium complexes/doi:10.1016%2FS0957-4166/rivista:Tetrahedron: asymmetry (Online)/anno:2001/pagina_da:2159/pagina_a:2167/intervallo_pagine:2159–2167/volume:12 |
| DOI: | 10.1016/S0957-4166 |
| Popis: | The ZnCl2-promoted cycloaddition of a series of enantiopure ortho-substituted benzaldehyde-Cr(CO)3 complexes and Danishefsky's diene gave the corresponding 2-aryl pyranones in good yields and complete enantiospecificity. Some of the mechanistic aspects of the cycloaddition were investigated and the reaction extended to different dienes |
| Databáze: | OpenAIRE |
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