Domino Diels-Alder reactions of 7-oxanorbornadiene-2, 3-dicarboximide: an elusive, highly reactive dienophile
| Autor: | Margetić, Davor, Butler, Douglas N., Warrener, Ron N., Murata, Yasujiro |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Popis: | Flash vacuum pyrolysis (FVP) has been used to generate the novel 7-oxa-norbornadiene-2, 3-dicarboxylic imide that in situ gave an unprecedented cycloaddition reaction cascade with the imidofuran, a sideproduct of FVP. Stereoselectivity of cycloadditions was studied with the aid of density functional calculations, which fully support observed exo/endo-selectivity. |
| Databáze: | OpenAIRE |
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