| Autor: |
Smrečki-Lolić, Neven, Đaković, Marijana, Popović, Zora |
| Přispěvatelé: |
Tomašić, Vesna, Maduna Valkaj, Karolina |
| Jazyk: |
chorvatština |
| Rok vydání: |
2011 |
| Předmět: |
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| Popis: |
Due to great interest in mimicking the active site of metalloproteins such as copper enzymes, a tremendous contribution to the development of new ideas and trends in coordination chemistry was done. In persuit of some of the ideas we synthesized copper(II) nitrate complexes with imidazole and γ-picoline as additional nitrogen ligands. The compounds were characterized by means of chemical analysis and IR-spectrometry, while the thermal stability was monitored by TG/DTA methods. The molecular and crystal structure of the imidazole complex was determined from the data of X-ray diffraction on single crystal sample. The molecular structure analysis revealed [4+2] coordination of the Cu(II) center, while the 2D supramolecular architecture is realized through the N—H···O hydrogen bonding network that is formed by fused R22(16) and R23(18) rings. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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