| Autor: |
Stipčić, Tea, Roca, Sunčica, Barišić, Lidija, Kovačević, Monika |
| Přispěvatelé: |
Dejanović, Igor, Vrsaljko Domagoj, Žižek, Krunoslav |
| Jazyk: |
chorvatština |
| Rok vydání: |
2020 |
| Předmět: |
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| Popis: |
The amide conjugates of 1, n-disubstituted ferrocenes and amino acids are well known for their ability to adopt the turn or -sheet-like structures [1-5], owing to the turn-inducing capacity of ferrocene scaffolds. Amide-to-ester substitutions in the peptide backbone have proven to be a good tool for evaluating of backbone hydrogen-bonding behaviour of the so-derived depsipeptides [6-7]. Herein, we describe the synthesis of depsipeptide analogue of the previously reported ferrocene peptides [2, 4]. The influence of the amide-to-ester substitution on the conformational properties of the depsipeptide 1 is explored by IR, NMR and CD spectroscopy. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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