Facile synthetic route to polymerizable hindered amine light stabilizers for transition-metal-catalyzed olefin copolymerization

Autor: Auer, Markku, Nicolas, R., Vesterinen, A., Luttikhedde, H., Wilen, Carl
Jazyk: angličtina
Rok vydání: 2004
Zdroj: Auer, M, Nicolas, R, Vesterinen, A, Luttikhedde, H & Wilen, C 2004, ' Facile synthetic route to polymerizable hindered amine light stabilizers for transition-metal-catalyzed olefin copolymerization ', Journal of Polymer Science, Part A: Polymer Chemistry, vol. 42, no. 6, pp. 1350-1355 . https://doi.org/10.1002/pola.11082
DOI: 10.1002/pola.11082
Popis: This work describes a facile method by which a polymerizable hindered amine light stabilizer, 4‐(10‐undecylidene)‐2,2,6,6‐tetramethylpiperidine, was prepared in a single‐step procedure by means of a Wittig reaction. The monomer was successfully copolymerized with ethylene with a rac‐[dimethylsilylenebis(4,5,6,7‐tetrahydro‐1‐indenyl)]zirconium dichloride/methylalumoxane catalyst system.
Databáze: OpenAIRE