| Autor: |
Koltunov, V. S., Taylor, Robin J., Gomonova, T.V., Savilova, O. A., Zhuravleva, G.I., Denniss, I.S. |
| Zdroj: |
Radiochimica Acta; July 2000, Vol. 88 Issue: 7 p425-430, 6p |
| Abstrakt: |
The oxidation of hydroxylamine by nitric acid in the presence of technetium ions at temperatures above ~60°C is an autocatalytic process comprising an induction period and then a catalysed reaction involving HNO2, which has accumulated in the solution. Tc ions have no appreciable effect on the reaction rate, which is governed only by the nitric and nitrous acid oxidation reactions of hydroxylamine, but the presence of Tc ions does extend the initial induction period. The rate of hydroxylamine oxidation by HNO3in the presence of HNO2, that is, after the induction period, was found to be: |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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