Coordination Chemistry of Isomeric Mixtures of Linked Di(phosphaguanidine) Compounds:  A Spectroscopic and Crystallographic Study

Autor: E. Mansfield, Natalie, P. Coles, Martyn, G. Avent, Anthony, B. Hitchcock, Peter
Zdroj: Organometallics; May 2006, Vol. 25 Issue: 10 p2470-2474, 5p
Abstrakt: Multinuclear NMR spectroscopy and X-ray diffraction techniques have been used to identify diastereomeric mixtures of rac- and meso-di(phosphaguanidine) compounds. A brief survey of their coordination chemistry has demonstrated the formation of N,N‘-bound bimetallic aluminum species and monometallic platinum complexes in which the ligand chelates to the metal through the two phosphorus donor atoms.
Databáze: Supplemental Index