| Autor: |
(Horasan) Kishali, Nurhan, Sahin, Ertan, Kara, Yunus |
| Zdroj: |
Organic Letters; April 2006, Vol. 8 Issue: 9 p1791-1793, 3p |
| Abstrakt: |
A new and stereospecific synthesis for bis-endoperoxide has been developed starting from tetrahydronaphthalene. Photooxygenation of tetrahydronaphthalene resulted in the formation of hydroperoxy-endoperoxide. The bromination reaction of hydroperoxy-endoperoxide gave bis-endoperoxide, whose exact configuration has been determined by X-ray analysis. The lowest-energy conformer of bis-endoperoxide is the boat-chair form. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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